Ultrafast Vibrational Dynamics of a Charged Aqueous Interface by Femtosecond Time-Resolved Heterodyne-Detected Vibrational Sum Frequency Generation

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<jats:title>Abstract</jats:title> <jats:p>Newly developed time-, frequency-, and phase-resolved heterodyne-detected vibrational sum frequency generation (TR-HD-VSFG) spectroscopy opens a new door to explore ultrafast vibrational dynamics of interfacial water. Here, we present the first observation of TR-HD-VSFG spectra of water at a charged monolayer/aqueous solution interface.</jats:p>

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