Hydrogenation of Phenol Using Silica-Supported Pd and PdAu Catalysts in the Presence of H2 and O2

• Shusuke Okada

  Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University

• Kensei Fujiwara

  Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University

• Takashi Kamegawa

  Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University

• Kohsuke Mori

  Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University

• Hiromi Yamashita

  Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University

Abstract

2-Cyclohexen-1-one can be synthesized from phenol using silica-supported Pd catalyst by hydrogenation under coexisting hydrogen and oxygen gases. The effects of hydrogen and oxygen ratio, solvent, and alloying Pd with Au were investigated. Similar transformations toward corresponding cyclic enones were observed in other phenolic compounds.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 85 (9), 1057-1059, 2012-09

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360565169050286592
• NII Article ID: 130004153111
• DOI: 10.1246/bcsj.20120118
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/85/9/1057/56274218/bcsj.20120118.pdf
• Data Source:
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  • CiNii Articles
  • KAKEN