High-Energy X-ray Diffraction Study on the Intramolecular Structure of 2-Aminoethanol in the Liquid State
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- Yasuo Kameda
- Department of Material and Biological Chemistry, Faculty of Science, Yamagata University
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- Hiroshi Deguchi
- Power Engineering R & D Center, Kansai Electric Power Co., Inc
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- Yoshiyuki Kubota
- Power Engineering R & D Center, Kansai Electric Power Co., Inc
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- Hirotoshi Furukawa
- Power Engineering R & D Center, Kansai Electric Power Co., Inc
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- Yasuyuki Yagi
- Power Engineering R & D Center, Kansai Electric Power Co., Inc
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- Yoshihiro Imai
- Power Engineering R & D Center, Kansai Electric Power Co., Inc
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- Masahiko Tatsumi
- Power Engineering R & D Center, Kansai Electric Power Co., Inc
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- Noriko Yamazaki
- Advanced Technology Research Center, Mitsubishi Heavy Industries Ltd
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- Noriko Watari
- Advanced Technology Research Center, Mitsubishi Heavy Industries Ltd
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- Takuya Hirata
- Hiroshima Research & Development Center, Mitsubishi Heavy Industries Ltd
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- Nobuyuki Matubayasi
- Institute of Chemical Research, Kyoto University
抄録
<jats:title>Abstract</jats:title> <jats:p>High-energy X-ray diffraction measurements were carried out for liquid 2-aminoethanol (NH2CH2CH2OH, MEA) in order to obtain direct information on the conformation of MEA in the liquid state, in which competition between intra- and intermolecular hydrogen bonds might occur. Least-squares fitting analysis was applied to the high-Q region of the observed total interference term with excellent statistical accuracies. Independent parameters, the C–C, C–O, and C–N interatomic distances, bond angles, ∠OCC and ∠CCN, and a dihedral angle ∠(NCC)–(CCO), were successfully obtained. It has been concluded that the MEA molecule takes the gauche conformation with the dihedral angle ∠(NCC)–(CCO) = 53(3)°, suggesting the formation of the intramolecular hydrogen bond is dominant in the liquid state.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 86 (1), 99-103, 2012-12-29
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360846644027009664
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- NII論文ID
- 130004153140
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- ISSN
- 13480634
- 00092673
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