Conversion of L-Cysteinato Rh[Ⅲ]₄Zn[Ⅱ]₄ Octanuclear to Rh[Ⅲ]₂Ag[Ⅰ]₃ Pentanuclear Structure by Ag[Ⅰ] Ions

• Yamashita Ukyo

  Department of Chemistry, Graduate School of Science, Osaka University

• Lee Pei-Shan

  Department of Chemistry, Graduate School of Science, Osaka University

• Kuwamura Naoto

  Department of Chemistry, Graduate School of Science, Osaka University

• Yoshinari Nobuto

  Department of Chemistry, Graduate School of Science, Osaka University

• Konno Takumi

  Department of Chemistry, Graduate School of Science, Osaka University

書誌事項

タイトル別名

• Conversion of <small>L</small>-Cysteinato Rh^III₄Zn^II₄ Octanuclear to Rh^III₂Ag^I₃ Pentanuclear Structure by Ag^I Ions
• Conversion of <scp>l</scp>-Cysteinato RhIII4ZnII4 Octanuclear to RhIII2AgI3 Pentanuclear Structure by AgI Ions

抄録

Treatment of a sulfur-bridged Rh^III₄Zn^II₄ octanuclear complex, (Δ)₄-K₆[(Zn₄O){Rh(L-cys-κ²N,S)₃}₄] (K₆[1]; H₂cys: cysteine) with Ag^I in an acidic aqueous medium gave a new Rh^III₂Ag^I₃ pentanuclear complex, (Δ)₂-H₄[Ag₃{Rh(L-cys-κ²N,S)₃}₂]NO₃ ([H₄2]NO₃). The structure in [H₄2]⁺ that possesses unique, multiple intermolecular interactions was determined by X-ray crystallography.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 86 (12), 1450-1452, 2013

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390282679118561024
• NII論文ID: 130004153169
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.20130200
• COI: 1:CAS:528:DC%2BC2cXntFSjtg%3D%3D
• ISSN: 13480634
• ISSN: 00092673
• NDL書誌ID: 025079993
• Web Site: http://id.ndl.go.jp/bib/025079993
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I025079993
• Web Site: https://academic.oup.com/bcsj/article-pdf/86/12/1450/56275764/bcsj.20130200.pdf
• 本文言語コード: en
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