Electron-Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals

• Kunio Awaga

  Research Center for Materials Science, Nagoya University

• Kenji Nomura

  Research Center for Materials Science, Nagoya University

• Hideo Kishida

  Department of Applied Physics, Graduate School of Engineering, Nagoya University

• Wataru Fujita

  Research Center for Materials Science, Nagoya University

• Hirofumi Yoshikawa

  Research Center for Materials Science, Nagoya University

• Michio M Matsushita

  Research Center for Materials Science, Nagoya University

• Laigui Hu

  Research Center for Materials Science, Nagoya University

• Yoshiaki Shuku

  Research Center for Materials Science, Nagoya University

• Rie Suizu

  Research Center for Materials Science, Nagoya University

Abstract

Heterocyclic thiazyl radicals possess unique chemical and physical properties as building blocks for molecule-based conductors and magnetic materials. They do not need protecting groups on their molecular skeletons, and the lack of such substituents permits close packing in the solid state. Moreover, thiazyl radical solids often involve a multidimensional network consisting of π–π overlaps and S···N contacts. The electronic structures of the thiazyl radicals can be compared to highly-correlated electron systems. In this account, we describe various electron-transfer processes in the solids of the thiazyl radicals, which manifest themselves by external stimuli such as temperature change, electric field, and photoillumination.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 87 (2), 234-249, 2014-02

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360283694073630720
• NII Article ID: 130004153276
• DOI: 10.1246/bcsj.20130248
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/87/2/234/56276757/bcsj.20130248.pdf
• Data Source:
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