炎光光度検出器付きガスクロマトグラフによる大気中の硫酸ミストの定量

• 松村 年郎

  国立衛生試験所環境衛生化学部

• 亀谷 勝昭

  国立衛生試験所環境衛生化学部

• 等々力 仁

  日穀製粉株式会社松本工場

• 竹村 忠憲

  上智社会福祉専門学校

• 留目 真理子

  株式会社エレナ

• 武田 明治

  国立衛生試験所環境衛生化学部

書誌事項

タイトル別名

• Determination of Sulfuric Acid Particles in the Atmosphere by a Gas Chromatograph with Flame Photometric Detector

抄録

Sulfuric acid particles in the atmosphere were collected on a teflon filter. The teflon filter was placed in a teflon-stoppered test tube and 10 ml of acetone was added to extract the particles. A 30 μl of diazomethane-ether solution was added to the sample so: ution. The test tube was shaken and made to stand for 30 min. Sulfuric acid was methylated with diazomethane at room temperat ure to dimethyl sulfate and determined by a gas chromatograph with a flame 'photometric detector.<BR>Diethyl sulfate was used as an internal stan dard for the determination of dimethyl sulfate. The detection limit of sulfuric acid particles by the proposed method was 0.1 μg/m³ in 5 m³ air. The present method was applied to the determination of sulfuric acid particles in the atmosphere at Setagaya-ku and Chiyoda-ku in Tokyo in December 1984 and JuneJuly 1985. The concentration of sulfuric acid particles, was found to be 0.2-1.2 μg/m³ and the value of [H₂SO₄]/[SO₄^2-] was 0.02-0.12.

収録刊行物

• 日本化学会誌（化学と工業化学）

  日本化学会誌（化学と工業化学） 1986 (1), 100-104, 1986-01-10

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204388899328
• NII論文ID: 130004158270
• DOI: 10.1246/nikkashi.1986.100
• ISSN: 21850925
• ISSN: 03694577
• Web Site: https://www.jstage.jst.go.jp/article/nikkashi1972/1986/1/1986_1_100/_pdf
• データソース種別:
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  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可