黒鉛負極上皮膜生成の電気化学AFMによる観察

• 山口 祥司

  三菱化学 (株) 坂出事業所技術開発部

書誌事項

タイトル別名

• <I>In-situ</I> Electrochemical AFM Observations of SEI Film Formation on Graphite Anodes

抄録

Solid Electrolyte Interphase (SEI) films play an important role in lithium ion battery. SEI films form ongraphite anode surfaces during early lithium intercalation process. SEI films prevent further solvent decompositionduring charge and discharge in the battery. Morphological study of SEI film formation is very important to understandthe function of SEI film in lithium ion battery system. Simultaneous in-situ electrochemical Atomic Force Microscopy (AFM) and Friction Force Microscopy (FFM) were successfully introduced to monitor SEI film formation in realtime. Topographic and frictional changes on the surface of a Highly Oriented Pyrolytic Graphite (HOPG) electrodein 1 mol/dm³ LiClO₄ EC/EMC (1:1) electrolyte were examined during charge and discharge. SEI film formationcommenced at approximately 2V vs. Li/Li⁺ and stable film formation with an island-like morphology was observedbelow approximately 0.9V vs. Li/Li⁺. Further experiments on a composite electrode made of synthetic graphite powderand polyvinylidene difluoride (PVDF) binder showed similar phenomena.

収録刊行物

• 炭素

  炭素 1999 (186), 39-44, 1999

  炭素材料学会

キーワード

• Lithium ion battery
• Graphite Intercalation Compound
• Anodes
• SEI
• in-situ electrochemical AFM

詳細情報

• CRID: 1390282679204541696
• NII論文ID: 130004358384
• DOI: 10.7209/tanso.1999.39
• ISSN: 18845495
• ISSN: 03715345
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可