External Heavy Atom Effect on Intersystem Crossing of Radical Pair in Solvent Cage. Photoreactions of Phthalazine

DOI PDF 参考文献8件
  • Hiroyasu Inoue
    Department of Applied Chemistry, Faculty of Technology, Kanagawa University
  • Tadamitsu Sakurai
    Department of Applied Chemistry, Faculty of Technology, Kanagawa University
  • Toshihiko Hoshi
    Department of Chemistry, College of Science and Engineering, Aoyma Gakuin University
  • Jun Okubo
    Department of Applied Science, Faculty of Engineering, Tokyo Denki University
  • Isao Ono
    Department of Chemistry, College of Science and Engineering, Aoyma Gakuin University

抄録

<jats:title>Abstract</jats:title> <jats:p>External heavy atom effects have been studied for the photoreaction of phthalazine in 2-propanol. Addition of bromine containing compounds alters the product distribution in the dual photoreactions occurred simultaneously. The results can be interpreted in terms of enhancement of the intersystem crossing from the triplet radical pair to the singlet radical pair, including the spin inversion within the solvent cage.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 19 (7), 1059-1062, 1990-07-01

    Oxford University Press (OUP)

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