Stereoselectivity in Intramolecular Cyclization of Non-conjugated Unsaturated Ketones by Electroreduction

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  • Ikuzo Nishiguchi
    Department of Chemistry, Nagaoka University of Technology1603-1, Kamitomioka-cho, Nagaoka, Niigata
  • Satoshi Goda
    Department of Chemistry, Nagaoka University of Technology1603-1, Kamitomioka-cho, Nagaoka, Niigata
  • Kouji Yamada
    Department of Chemistry, Nagaoka University of Technology1603-1, Kamitomioka-cho, Nagaoka, Niigata
  • Yoshimasa Yamamoto
    Department of Chemistry, Nagaoka University of Technology1603-1, Kamitomioka-cho, Nagaoka, Niigata
  • Hirofumi Maekawa
    Department of Chemistry, Nagaoka University of Technology1603-1, Kamitomioka-cho, Nagaoka, Niigata

抄録

<jats:title>Abstract</jats:title> <jats:p>This study showed some decrease in stereoselectivity in electroreductive intramolecular cyclization of nitrogen-containing non-conjugated enones in comparison with high stereoselectivity for the corresponding enones possessing an all-carbon-chain or a sulfur-containing chain. This phenomenon may provide some actual experimental supports for the remarkable stereochemical features of the electroreductive cyclization.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 31 (12), 1254-1255, 2002-12-01

    Oxford University Press (OUP)

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