Catalytic, Enantioselective Propargyl- and Allenylation Reactions of α-Imino Ester

  • Hirotaka Kagoshima
    Department of Chemistry, Faculty of Science, Gakushuin University1-5-1 Mejiro, Toshima-ku, Tokyo
  • Tetsumaru Uzawa
    Department of Chemistry, Faculty of Science, Gakushuin University1-5-1 Mejiro, Toshima-ku, Tokyo
  • Takahiko Akiyama
    Department of Chemistry, Faculty of Science, Gakushuin University1-5-1 Mejiro, Toshima-ku, Tokyo

抄録

<jats:title>Abstract</jats:title> <jats:p>Catalytic, enantioselective propargyl- and allenylation reactions of α-imino ester have been achieved by means of the [Cu(MeCN)4]ClO4/(R)-tol-BINAP catalyst to afford the corresponding propargyl- and allenyl-substituted α-amino acid derivatives, respectively, in good yields with good enantiomeric excesses.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 31 (3), 298-299, 2002-03-01

    Oxford University Press (OUP)

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