Cluster Core Expansion through Incorporation of Transition-metal Fragments or an Alkyne Molecule into an Incomplete Cubane-type Fe2RuS4 Cluster

• Masaaki Okazaki

  Department of Chemistry, Graduate School of Science, Tohoku University

• Atsushi Sakuma

  Department of Chemistry, Graduate School of Science, Tohoku University

• Hiromi Tobita

  Department of Chemistry, Graduate School of Science, Tohoku University

• Hiroshi Ogino

  Miyagi Study Center, University of the Air

Abstract

Treatment of CpS22Fe2S4 (CpS2 = 1,3-C5H3(SiMe3)2) with [CpRu(MeCN)3]+ in acetonitrile at room temperature led to the formation of an incomplete cubane-type cluster [(CpS2Fe)2(CpRu)S4]+ (1). Further treatment of 1 with [Cp′Ru(MeCN)3]+ (Cp′ = Cp, Cp*) produced [(CpS2Fe)2(CpRu)(Cp′Ru)S4]2+. Cluster 1 reacted with DMAD to give the 1:1 adduct through formation of three sulfur–carbon bonds.

Journal

• Chemistry Letters

  Chemistry Letters 33 (9), 1130-1131, 2004-08-07

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644040501376
• NII Article ID: 130004423614
• DOI: 10.1246/cl.2004.1130
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/33/9/1130/55582744/cl.2004.1130.pdf
• Data Source:
  • Crossref
  • CiNii Articles