Effective scCO2-ionic Liquid Reaction System Based on Symmetric Aliphatic Ammonium Salts for the Rapid CO2 Fixation with Aziridine to 2-Oxazolidinone
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- Hajime Kawanami
- Supercritical Fluid Research Center, National Institute of Advanced Science and Technology, and CREST, Japan Science and Technology
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- Hajime Matsumoto
- Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Science and Technology
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- Yutaka Ikushima
- Supercritical Fluid Research Center, National Institute of Advanced Science and Technology, and CREST, Japan Science and Technology
抄録
<jats:title>Abstract</jats:title> <jats:p>The hybrid reaction system composed of supercritical carbon dioxide and room temperature ionic liquid based on symmetric tetraalkyl ammonium salts can effectively promote the carbon dioxide fixation from aziridine to 2-oxazolidinone in the presence of iodine in high yield of 98% within 5 min. The TOF value under this condition is 254 times larger than that using conventional organic solvent.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 34 (1), 60-61, 2004-12-11
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360565169064106496
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- NII論文ID
- 130004423636
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- ISSN
- 13480715
- 03667022
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- データソース種別
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