Optically Transparent Thin Film of Layered Niobate (K4Nb6O17) Intercalated with Tris(2,2′-bipyridyl)ruthenium(II)

• Zhiwei Tong

  Department of Applied Chemistry, Graduate Course of Engineering, Tokyo Metropolitan University

• Shinsuke Takagi

  Department of Applied Chemistry, Graduate Course of Engineering, Tokyo Metropolitan University

• Hiroshi Tachibana

  Department of Applied Chemistry, Graduate Course of Engineering, Tokyo Metropolitan University

• Katsuhiko Takagi

  Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University

• Haruo Inoue

  Department of Applied Chemistry, Graduate Course of Engineering, Tokyo Metropolitan University

Abstract

A unique guest–guest ion exchange method was developed for preparing a thin film of a nano-layered K4Nb6O17·3H2O that possesses both 1) optical transparency and 2) ion-exchangeability, the first example of such a material. An optically transparent Ru(bpy)32+–K4Nb6O17 hybrid thin film, a potential photo-responsive electrode, was successfully prepared by the guest–guest exchange method by use of the intercalation compound MV2+–K4Nb6O17 as a precursor.

Journal

• Chemistry Letters

  Chemistry Letters 34 (4), 608-609, 2005-03-19

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360002219110686336
• NII Article ID: 130004423877
• DOI: 10.1246/cl.2005.608
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/34/4/608/55587472/cl.2005.608.pdf
• Data Source:
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  • CiNii Articles