Hypervalent Silicon and Phosphorus Atoms in Single Molecules: Synthesis and Properties of Phosphoranylalkoxysilicates and a Phosphoranyloxysilicate

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  • Naokazu Kano
    Department of Chemistry, Graduate School of Science, The University of Tokyo
  • Hideaki Miyake
    Department of Chemistry, Graduate School of Science, The University of Tokyo
  • Takayuki Kawashima
    Department of Chemistry, Graduate School of Science, The University of Tokyo

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<jats:title>Abstract</jats:title> <jats:p>The first hypervalent compounds containing both a pentacoordinated silicon atom and a pentacoordinated phosphorus atom were synthesized by the cooperative three-component reaction of a phosphoranide, a silane, and THF accompanying the ring opening of THF, or by the nucleophilic addition of phosphoranylalkoxides to a silane. Hydrolysis of the phosphoranyloxysilicate and phosphoranylalkoxysilicates gave the hydroxysilicate and the corresponding phosphoranes.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 36 (10), 1260-1261, 2007-09-22

    Oxford University Press (OUP)

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