Ordered Microdomain of Diprotonated Tetraphenylporphine Aggregate Formed at Dodecane/Aqueous H2SO4 Interface Measured by Microspectrophotometry

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  • Yukio Kamiya
    Department of Chemistry, Graduate School of Science, Hiroshima University
  • Satoshi Tsukahara
    Department of Chemistry, Graduate School of Science, Hiroshima University
  • Terufumi Fujiwara
    Department of Chemistry, Graduate School of Science, Hiroshima University

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<jats:title>Abstract</jats:title> <jats:p>In situ microscopic measurements showed that rhombic microdomains of diprotonated 5,10,15,20-tetraphenylporphine aggregates were formed at a dodecane/aqueous H2SO4 interface. The size and thickness of the microdomains were about 10–100 μm and a monolayer level, respectively. The microscopic absorption anisotropy of individual microdomains revealed that they had an ordered structure, like single crystals.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 36 (2), 344-345, 2007-02-01

    Oxford University Press (OUP)

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