A Novel Vanadyl Alkylporphyrins from Geological Samples: A Possible Derivative of Divinylchlorophylls or Bacteriochlorophyll <i>a</i>?
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- Yuichiro Kashiyama
- Institute for Research on Earth Evolution, Japan Agency for Marine-Earth Science and Technology
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- Motoo Shiro
- X-ray Research Laboratory, Rigaku Co
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- Ryuji Tada
- Department of Earth and Planetary Science, The University of Tokyo
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- Naohiko Ohkouchi
- Institute for Research on Earth Evolution, Japan Agency for Marine-Earth Science and Technology
Abstract
<jats:title>Abstract</jats:title> <jats:p>A novel C30 vanadyl alkylporphyrins, 13,15-ethano-3-ethyl-2,7,12,18-tetramethylporphyrin (i.e., 8-nor-deoxophylloerythroetioporphyrin; 8-nor-DPEP) has been isolated from a Middle Miocene siliceous shale. The structure of intact vanadyl porphyrins was determined by X-ray crystallography. The structure suggests it to be originated from specific chloropigments such as chlorophylls a2, b2, c2, and c3 or bacteriochlorophyll a, hence potentially being a biomarker of specific photoautotrophs.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 36 (6), 706-707, 2007-04-28
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360283694087743360
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- NII Article ID
- 130004424751
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles