Thiofluorination of Carbon–Carbon Multiple Bonds Using Electrochemically Generated ArS(ArSSAr)+BF4−

• Shunsuke Fujie

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

• Kouichi Matsumoto

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

• Seiji Suga

• Jun-ichi Yoshida

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

Abstract

The reaction of alkenes and alkynes with ArS(ArSSAr)+BF4−, which was generated and accumulated by the low-temperature anodic oxidation of ArSSAr in Bu4NBF4/CH2Cl2, led to the addition of an ArS group and fluoride across the carbon–carbon multiple bond to give thiofluorinated compounds in good yields.

Journal

• Chemistry Letters

  Chemistry Letters 38 (12), 1186-1187, 2009-11-21

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360283694087945984
• NII Article ID: 130004425418
• DOI: 10.1246/cl.2009.1186
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/38/12/1186/55601329/cl.2009.1186.pdf
• Data Source:
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  • CiNii Articles