A Cycloalkane-based Thermomorphic System for Organocatalytic Cyclopropanation Using Ammonium Ylides

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  • Shokaku Kim
    Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology
  • Naoki Ikuhisa
    Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology
  • Kazuhiro Chiba
    Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology

Abstract

<jats:title>Abstract</jats:title> <jats:p>Highly polar ammonium ylide intermediates derived from α-halocarbonyl compounds were successfully trapped by cycloalkane phase-tagged activated alkenes via a cycloalkane-based thermomorphic (CBT) process, which allows for facile product isolation using a single liquid–liquid extraction step to effectively generate cyclopropane libraries in the cyclohexane phase.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 40 (10), 1077-1078, 2011-09-17

    Oxford University Press (OUP)

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