An Electrostatic Model for the Unusual Salt Effect on the Stability of Ionic Copolymer Micelles

• Hiroshi Maeda

  Kyushu University

抄録

An interesting observation reported that the critical micelle concentrations of an ionic amphiphilic block copolymer increased with the salt concentration. Numerical solutions of the Poisson–Boltzmann equations for polyelectrolyte brushes have suggested the existence of a region of approximately zero net charges close to the nonpolar core surface. The observed unusual salt effect could be explained if a kind of counter ion condensation is assumed in this region.

収録刊行物

• Chemistry Letters

  Chemistry Letters 41 (10), 1057-1059, 2012-09-15

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169065024000
• NII論文ID: 130004426331
• DOI: 10.1246/cl.2012.1057
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/41/10/1057/55637400/cl.2012.1057.pdf
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