Local Thermal Nonequilibrium on Solid and Liquid Interface Generated in a Microwave Magnetic Field

DOI PDF 被引用文献6件 参考文献21件
  • Dai Mochizuki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Masashi Shitara
    Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Masato Maitani
    Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Yuji Wada
    Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology

抄録

<jats:title>Abstract</jats:title> <jats:p>Dehalogenation of (2-haloethyl)benzene using Fe particles was carried out in the electric and magnetic fields in a microwave single mode cavity. Microwave irradiation in a magnetic field enhanced the conversion of (2-haloethyl)benzene compared with heating by a mantle heater and microwave in an electric field, while the ethylbenzene selectivities were comparable. Larger Fe particles generated sparks under microwave irradiation, resulting in the increase of ethylbenzene selectivities. These data suggested the reaction acceleration by a local thermal nonequilibrium in the solid–liquid system by the selective microwave heating of the solid.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 41 (11), 1409-1411, 2012-10-27

    Oxford University Press (OUP)

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