Nickel-catalyzed Decarbonylative Polymerization of 5-Alkynylphthalimides: A New Methodology for the Preparation of Polyheterocycles

• Takeuchi Makoto

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Kurahashi Takuya

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University JST, ACT-C

• Matsubara Seijiro

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

Abstract

A nickel-catalyzed decarbonylative cycloaddition was developed, in which 5-alkynylphthalimides reacted to afford a new type of polyisoquinolone. It was demonstrated for the first time that decarbonylative cycloaddition can be an elementary process of polycondensation for the preparation of heterocyclic polymers.

Journal

• Chemistry Letters

  Chemistry Letters 41 (12), 1566-1568, 2012

  The Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1390282679564468352
• NII Article ID: 130004426443
• DOI: 10.1246/cl.2012.1566
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/41/12/1566/55640584/cl.2012.1566.pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed