Halide-controlled Construction and Structural Determination of a Series of Thiolato-bridged 16-Nuclear Copper(I) Clusters from Benzothiazoline

• Takino Yusuke

  Department of Chemistry, Graduate School of Science, Osaka University

• Yoshinari Nobuto

  Department of Chemistry, Graduate School of Science, Osaka University

• Tsuge Kiyoshi

  Department of Chemistry, Graduate School of Science and Engineering, University of Toyama

• Kawamoto Tatsuya

  Department of Chemistry, Faculty of Science, Kanagawa University

• Konno Takumi

  Department of Chemistry, Graduate School of Science, Osaka University

抄録

Treatment of [Cu(CH₃CN)₄]⁺ with 2-(4-dimethylaminophenyl)benzothiazoline in the presence of halide ions (X = Cl⁻, Br⁻, and I⁻) gave [Cu₁₆L₁₂X]³⁺ (L = (C₆H₄NMe₂)CH=N(C₆H₄)S⁻) with a spherical Cu₁₆S₁₂ structure, while similar treatment in the absence of halide ions afforded [Cu₈L₈]²⁺ with a cyclic Cu₈S₈ structure.

収録刊行物

• Chemistry Letters

  Chemistry Letters 41 (3), 334-336, 2012

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390282679563768064
• NII論文ID: 130004426539
• DOI: 10.1246/cl.2012.334
• COI: 1:CAS:528:DC%2BC38XkvVOjsL8%3D
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/41/3/334/55638600/cl.2012.334.pdf
• 本文言語コード: en
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