Thiolato-bridged AuI2CuI2 and CuI4 Metallorings Derived from Benzothiazoline: Can Gold(I) Plus Copper(I) Make Silver(I)?

DOI PDF 参考文献11件
  • Yusuke Takino
    Department of Chemistry, Graduate School of Science, Osaka University
  • Nobuto Yoshinari
    Department of Chemistry, Graduate School of Science, Osaka University
  • Tatsuya Kawamoto
    Department of Chemistry, Faculty of Science, Kanagawa University
  • Takumi Konno
    Department of Chemistry, Graduate School of Science, Osaka University

抄録

<jats:title>Abstract</jats:title> <jats:p>A thiolato-bridged AuI2CuI2 metalloring compound, [Au2Cu2(L)4] (L = (C6H4NMe2)CH=N(C6H4)S−), together with an analogous CuI4 compound, [Cu4(L)4], was newly prepared from 2-(4-dimethylaminophenyl)benzothiazoline. The AuI2CuI2 compound was found to show structural and spectroscopic features comparable well with those of [Ag4(L)4], rather than those of [Au4(L)4] and [Cu4(L)4].</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 41 (8), 834-836, 2012-08-01

    Oxford University Press (OUP)

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