Practical Optical Resolution of Planar Chiral Pseudo-<i>ortho</i>-disubstituted [2.2]Paracyclophane

DOI PDF 被引用文献30件 参考文献35件
  • Yasuhiro Morisaki
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
  • Ryoyu Hifumi
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
  • Lin Lin
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
  • Kenichi Inoshita
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
  • Yoshiki Chujo
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University

抄録

<jats:title>Abstract</jats:title> <jats:p>We describe the practical optical resolution of rac-pseudo-ortho-dibromo[2.2]paracyclophane to obtain the parent compound for a variety of cyclophane-based planar chiral compounds such as enantiopure chiral ligand [2.2]PHANEPHOS. In addition, the obtained enantiopure planar chiral (R)- and (S)-pseudo-ortho-disubstituted [2.2]paracyclophanes can be used as the building blocks for optically active carbon-rich compounds.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 41 (9), 990-992, 2012-09

    Oxford University Press (OUP)

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