(3-Fluoro-4-methoxyanilinium)+([18]Crown-6) Supramolecular Cation Salt of Ferromagnetic [MnIICrIII(oxalate)3]−

• Toru Endo

  Graduate School of Environmental Science, Hokkaido University

• Kazuya Kubo

  Graduate School of Environmental Science, Hokkaido University

• Masashi Yoshitake

  Graduate School of Environmental Science, Hokkaido University

• Shin-ichiro Noro

  Graduate School of Environmental Science, Hokkaido University

• Tomoyuki Akutagawa

  Institute of Multidisciplinaly Research for Advanced Materials, Tohoku University

• Takayoshi Nakamura

  Graduate School of Environmental Science, Hokkaido University

抄録

A single crystal of (3-fluoro-4-methoxyanilinium)+([18]crown-6)[MnIICrIII(oxalate)3]−(CH3OH)2 had the space group Cc owing to the arrangement of the 3-fluoro-4-methoxyanilinium+ cation with C1 symmetry and, therefore, was pyroelectric. A ferromagnetic transition at 5.5 K was observed, which originated from the two-dimensional honeycomb structure of the [MnIICrIII(oxalate)3]− anion.

収録刊行物

• Chemistry Letters

  Chemistry Letters 42 (2), 137-139, 2013-01-26

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644041875328
• NII論文ID: 130004426850
• DOI: 10.1246/cl.2013.137
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/42/2/137/55637074/cl.2013.137.pdf
• データソース種別:
  • Crossref
  • CiNii Articles
  • KAKEN