Acetals of <i>N</i>,<i>N</i>-Dimethylformamides: Ambiphilic Behavior in Converting Carbon Dioxide to Dialkyl Carbonates

DOI PDF 被引用文献3件 参考文献29件
  • Yuki Takada
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Aki Matsuoka
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Ya Du
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Hiroshi Naka
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Susumu Saito
    Department of Chemistry, Graduate School of Science, Nagoya University

抄録

<jats:title>Abstract</jats:title> <jats:p>Carbon dioxide is immobilized into dialkyl carbonate using acetals of N,N-dimethylformamide under atmospheric pressure. No special treatment with tailor-made catalysts is needed. Use of dimethyl sulfoxide as a solvent is critical. An ambiphilic mechanism is proposed for the direct synthesis of dialkyl carbonates from acetals and carbon dioxide.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 42 (2), 146-147, 2013-01-26

    Oxford University Press (OUP)

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