Crystal Structure and Solid-state Ionic Conductivity of Cyclic Sulfonylamide Salts with Cyano-substituted Quaternary Ammonium Cations

Abstract

<jats:title>Abstract</jats:title> <jats:p>Novel organic ionic plastic crystals containing cyclic perfluorosulfonylamide anions were synthesized by anion metathesis between a cyano-functionalized quaternary ammonium halide and Li[N(SO2CF2)2CF2] (LiCPFSA). The structure of [N(CH3)2(CH2CN)2][CPFSA] was disclosed by single-crystal X-ray diffraction study. This is the first report on the crystal structure of cyclic perfluorosulfonylamide anion.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 43 (1), 108-110, 2013-10-16

    Oxford University Press (OUP)

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