HREELS Evaluation of Coronene Monolayer Adsorption on Au(111) as the First Base Layer to Achieve Coordination Programming

  • Nishiyama Katsuhiko
    Graduate School of Science and Technology, Kumamoto University Kumamoto Institute for Photo-Electro Organics (PHOENICS)
  • Harada Hiroshi
    Graduate School of Science and Technology, Kumamoto University
  • Yoshimoto Soichiro
    Priority Organization for Innovation and Excellence, Kumamoto University Kumamoto Institute for Photo-Electro Organics (PHOENICS)
  • Taniguchi Isao
    Graduate School of Science and Technology, Kumamoto University
  • Yamada Taro
    School of Engineering, The University of Tokyo

抄録

To achieve coordination programming at an electrode surface, the first functional layer is highly important. In this study, high-resolution electron energy-loss spectroscopy (HREELS) was used to investigate coronene monolayer adsorption on a Au(111) substrate at 300 K. In the spectra, only a band attributable to the out-of-plane vibration mode was observed, suggesting that coronene molecules adsorb on the substrate with a flat orientation. Furthermore, the HREEL spectra showed that the coronene monolayer was stable even after heating to 400 K.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 43 (8), 1340-1342, 2014

    公益社団法人 日本化学会

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