Eclipsed Columnar Packing in Crystal Structure of Sumanenetrione

  • Binod Babu Shrestha
    Department of Functional Molecular Science, School of Physical Sciences, The Graduate University for Advanced Studies
  • Yuki Morita
    Research Center of Integrative Molecular Systems, Institute for Molecular Science
  • Tatsuhiro Kojima
    Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH)
  • Masaki Kawano
    Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH)
  • Shuhei Higashibayashi
    Department of Functional Molecular Science, School of Physical Sciences, The Graduate University for Advanced Studies
  • Hidehiro Sakurai
    Department of Functional Molecular Science, School of Physical Sciences, The Graduate University for Advanced Studies

Abstract

<jats:title>Abstract</jats:title> <jats:p>Single crystals of sumanenetrione and the iodinated derivative were found to possess a columnar packing structure with characteristic eclipsed stacks in a convex-to-concave fashion. In each column, the molecules are perfectly stacked without twisting and slipping in contrast to pristine sumanene. The neighboring columns are arranged in the opposite directions.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 43 (8), 1294-1296, 2014-05-10

    Oxford University Press (OUP)

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