Interface Electronic Structure of Zinc-Phthalocyanine on the Silver Thin-Film Quantum-Well

  • Nakayama Yasuo
    Center for Frontier Science, Chiba University, Japan
  • Lin Meng-Kai
    Department of Physics and Astronomy, National Tsing-Hua University, Republic of China
  • Wang Chin-Yung
    Department of Physics and Astronomy, National Tsing-Hua University, Republic of China
  • Pi Tun-Wen
    National Synchrotron Radiation Research Center (NSRRC), Republic of China
  • Ishii Hisao
    Center for Frontier Science, Chiba University, Japan Graduate school of Advanced Integration Science, Chiba University, Japan
  • Tang S.-J.
    Department of Physics and Astronomy, National Tsing-Hua University, Republic of China National Synchrotron Radiation Research Center (NSRRC), Republic of China

抄録

Electronic structures of a novel interface formed by coverage of organic semiconductor zinc-phthalocyanine (ZnPc) onto a nanometer-thick Ag thin-film with quantized electronic states were investigated by means of angle-resolved photoelectron spectroscopy (ARPES). While the highest occupied molecular orbital position of ZnPc accords with those of a ZnPc overlayer on a bulk Ag substrate having been reported previously, an interface state (IS) revealed different energy position with respect to the bulk case. Absence of the angular-dependence of the IS position strongly suggests that this state is localized at each ZnPc molecule. [DOI: 10.1380/ejssnt.2012.149]

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