AC impedance of multi-walled carbon nanotubes

  • Tsutsui Makusu
    The Institute of Scientific and Industrial Research, Osaka University, Japan
  • Kuno Keishi
    Department of Materials Science and Engineering, Kyoto University, Japan
  • Kurokawa Shu
    International Innovation Center, Kyoto University, Japan
  • Sakai Akira
    International Innovation Center, Kyoto University, Japan

抄録

We have placed a multi-walled carbon nanotube (MWNT) on a pair of nano-gapped electrodes and measured its AC impedance at room temperature for frequencies up to 200 kHz. The real part of the impedance ReZ displayed no characteristic features while the imaginary part ImZ exhibited a transition from capacitive to inductive behaviors around 50 kHz. Both ReZ and ImZ spectra show no substantial changes with varying the electrode gap distance and changing the atmosphere from air to vacuum. On the other hand, upon increasing the DC bias. the whole ImZ spectral curve shifts upward to higher impedances while ReZ displays little bias dependence. We found that the inductive behavior of ImZ above 100 kHz has a negative correlation with the low-bias DC conductance of MWNTs, which approximately represents the contact conductance between MWNTs and the electrodes. This result indicates that the MWNT-electrode interface determines the inductive part of ImZ. [DOI: 10.1380/ejssnt.2007.12]

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