Polarized ff-emission of terbium(3) by using the stretched polymer film technique

  • Hasegawa Miki
    Department of Chemistry and Biological Science, Aoyama Gakuin Univeristy Institute for Molecular Science Research Center for Advanced Science and Technology, The University of Tokyo
  • Ishi Ayumi
    Department of Chemistry and Biological Science, Aoyama Gakuin Univeristy
  • Furukawa Koichiro
    Department of Chemistry and Biological Science, Aoyama Gakuin Univeristy
  • Ohtsu Hideki
    Department of Chemistry and Biological Science, Aoyama Gakuin Univeristy

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  • Polarized ff-Emission of Terbium(III) by using the Stretched Polymer Film Technique

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A Novel coordination system with ff-emission of Tb(III) was obtained on a polyvinyl alcohol (PVA) film surface. On this film the ff-emission is polarized, and is intensified by polymer stretching. XAFS spectra show that the mean bond distances between Tb(III) and the nearest neighbour atoms of the 1,10,-phenanthroline ligand on the film are close to those in [Tb(SA)3], Tb(NO3)H2O and [Tb(phen)2(NO3)3].

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