An efficient strategy for enhancing the photosensitivity of photochromic 〔2.2〕paracyclophane-bridged imidazole dimers

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  • Muyoh Katsuya
    Department of Chemistry, School of Science and Engineering, Aoyama Gakuin Universiy,
  • Hatano Sayaka
    Department of Chemistry, School of Science and Engineering, Aoyama Gakuin Universiy,
  • Abe Jiro
    Department of Chemistry, School of Science and Engineering, Aoyama Gakuin Universiy,

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  • An Efficient Strategy for Enhancing the Photosensitivity of Photochromic [2.2]Paracyclophane-Bridged Imidazole Dimers

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We describe an efficient strategy for designing high-performance fast-photochromic molecules with increased photosensitivity to solar UVA radiation. The photosensitivity of [2.2]paracyclophane-bridged imidazole dimers can be readily enhanced through appropriate design of the phenyl rings attached to the imidazole rings. The diversity of the molecular design and the ease of synthesis make this class of photochromic molecules highly attractive for high-performance ophthalmic plastic lenses.

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