CSI-MS Measurement of Lanthanide-Series Ionic Probes for Ionic Probe Attachment Ionization

  • ITO Fumihiro
    Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University
  • NAKAMURA Tomoko
    Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University
  • YAMAGUCHI Kentaro
    Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University

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抄録

We have developed a new ionization method called ‘ionic probe attachment ionization,’ which uses lanthanide-complex-based ionic probes containing tetramethyl 2,6-bis(oxazolinyl)pyridine (TMpybox) ligands. Cold-spray ionization mass spectra of the lanthanide-series ionic probes are presented using NHS-TMpybox-binding lysine. The coordination ability of lanthanides, which is a fundamental property of these metals, was estimated by determining the stability of each complex at low spray temperature.

収録刊行物

  • 質量分析

    質量分析 60 (2), 33-36, 2012

    一般社団法人 日本質量分析学会

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