Adsorption Structure of Adipic Acid on Cu(110) Surfaces

• YAGYU Shinjiro

  Nanomaterials Laboratory, National Institute for Materials Science

• YOSHITAKE Michiko

  Nanomaterials Laboratory, National Institute for Materials Science

• CHIKYOW Toyohiro

  Nanomaterials Laboratory, National Institute for Materials Science

Bibliographic Information

Other Title

• Ｃｕ（１１０）表面でのアジピン酸の吸着状態
• Cu 110 ヒョウメン デ ノ アジピンサン ノ キュウチャク ジョウタイ

Abstract

We have investigated thermal stability and adsorption structure of adipic acid (HOOC-(CH₂)₄-COOH) on Cu(110) surfaces as a function of sample temperature using temperature programmed desorption (TPD), low energy electron diffraction (LEED) and fourier transform infrared adsorption spectroscopy (FT-IRAS). From 350 to 400 K, adipic acid adsorbed as monoadipiate (HOOC-(CH₂)₄-COO⁻) forms corresponding structure of c(2×2). As the temperature increases until about 600 K, monoadipiate changes to biadipiate (⁻OOC-(CH₂)₄-COO⁻) corresponding structure of p(1×2) or p(6×2). Biadipiate structure is stable until 600 K and then desorption occurred.

Journal

• Hyomen Kagaku

  Hyomen Kagaku 26 (9), 510-513, 2005

  The Surface Science Society of Japan

Details

• CRID: 1390001206459293568
• NII Article ID: 130004486282
• NII Article ID: 40006907365
• NII Book ID: AN00334149
• DOI: 10.1380/jsssj.26.510
• COI: 1:CAS:528:DC%2BD2MXht1ensr7J
• ISSN: 18814743
• ISSN: 03885321
• ISSN: http://id.crossref.org/issn/03885321
• NDL BIB ID: 7478785
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7478785
• Web Site: http://www.jstage.jst.go.jp/article/jsssj/26/9/26_9_510/_pdf
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed