Direct Observation of Conformational Isomers of (CH<sub>3</sub>S)<sub>2</sub> Molecules on Cu (111)

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  • Ohara Michiaki
    Surface Chemistry Laboratory RIKEN (The Institute of Physical and Chemical Research)
  • Kim Yousoo
    Surface Chemistry Laboratory RIKEN (The Institute of Physical and Chemical Research)
  • Kawai Maki
    Surface Chemistry Laboratory RIKEN (The Institute of Physical and Chemical Research)

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  • Direct Observation of Conformational Isomers of (CH3S)2 Molecules on Cu (111)

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Scanning tunneling microscope (STM) images of isolated molecules of dimethyl disulfide, (CH3S)2, adsorbed on a Cu (111) surface were successfully obtained at a sample temperature of 4.7 K. A (CH3S)2 molecule appears as an elliptic protrusion in the STM images. The STM images of (CH3S)2 molecules revealed that the molecules have a total of six equivalent adsorption orientations on Cu (111), which are given by the combination of three equivalent adsorption sites and two conformational isomers for each adsorption site.

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