Thin Film Structures of Metal-Organic Framework [Cu<sub>3</sub>(BTC)<sub>2</sub>(H<sub>2</sub>O)<sub>3</sub>]<i><sub>n</sub></i> on TiO<sub>2</sub>(110)

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  • HASHIMOTO Miyuki
    Graduate School of Humanities and Sciences, Ochanomizu University
  • OKAJIMA Satoshi
    Graduate School of Arts and Sciences, International Christian University
  • KONDO Toshihiro
    Graduate School of Humanities and Sciences, Ochanomizu University
  • HARA Kenji
    Catalysis Research Center, Hokkaido University
  • CHUN Wang-Jae
    Graduate School of Arts and Sciences, International Christian University

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  • Thin Film Structures of Metal-Organic Framework [Cu₃(BTC)₂(H₂O)₃]n on TiO₂(110)

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Abstract

Thin film structures of [Cu3(BTC)2(H2O)3]n (HKUST-1), which is one of Metal-organic frameworks (MOFs), prepared via step-by-step liquid phase epitaxy (LPE) method, on a TiO2(110) surface were investigated by polarization-dependent total reflection fluorescence X-ray absorption fine structure (PTRF-XAFS), X-ray diffraction (XRD), and scanning electron microscopy (SEM). For the ultra thin film, PTRF-XAFS enlightened that HKUST-1 eventually formed even at 1 cycle LPE. For further growth, XRD and SEM verified well-oriented < 111 > HKUST-1 thin films on the surface. These results proposed that the adsorption structure of linkers on the surface plays an important role to control the orientation of MOF films.

Journal

  • Electrochemistry

    Electrochemistry 82 (5), 335-337, 2014

    The Electrochemical Society of Japan

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