sigma-Bonded Dimeric Structure of Condensed Polycyclic Neutral Radical and its Dynamic Behavior: Synthesis and Properties of Oxophenalenedioxyl Derivative

• Suzuki Shuichi

  Graduate School of Science, Osaka University Graduate School of Science, Osaka City University

• Morita Yasushi

  Graduate School of Science, Osaka University PREST-JST

• Yoshida Kenta

  Graduate School of Science, Osaka University

• Fukui Kozo

  PREST-JST

• Shiomi Daisuke

  Graduate School of Science, Osaka City University

• Sato Kazunobu

  Graduate School of Science, Osaka City University

• Takui Takeji

  Graduate School of Science, Osaka City University

• Nakasuji Kazuhiro

  Graduate School of Science, Osaka University Fukui University of Technology

Bibliographic Information

Other Title

• 縮合多環型中性ラジカルのσ-結合型二量体構造と動的挙動：オキソフェナレンジオキシルの合成と性質

Abstract

For the purpose of syntheses of novel stable neutral radicals and generation of unique properties, we have designed and synthesized various neutral radicals based on the phenalenyl system. Recently, we have designed a highly symmetrical neutral diradical based on phenalenyl skeleton, and challenged its synthesis. We have succeeded in the synthesis of the radical precursor by the regioselective introduction of an oxygen atom into the phenalenone skeleton. In this presentation, we discuss structures and dynamic behaviors of a compound prepared by oxidation of the precursor.

Journal

• Abstracts of Symposium on Physical Organic Chemistry

  Abstracts of Symposium on Physical Organic Chemistry 2008 (0), 379-379, 2008

  The Society of Physical Organic Chemistry, Japan

Keywords

• neutral open-shell molecule
• oxophenalenoxyl
• diradical
• DImeric Structure

Details

• CRID: 1390282680533486976
• NII Article ID: 130004645512
• DOI: 10.11494/kisoyuki.2008.0.379.0
• Text Lang: ja
• Data Source:
  • JaLC
  • CiNii Articles
• Abstract License Flag: Disallowed