Thiazole-fused Benzothiadiazole as a Key Skeleton for T-Shaped Electron-accepting Building Blocks

• Motoi Satou

  Institute for Chemical Research, Kyoto University

• Kensuke Uchinaga

  Institute for Chemical Research, Kyoto University

• Atsushi Wakamiya

  Institute for Chemical Research, Kyoto University

• Yasujiro Murata

  Institute for Chemical Research, Kyoto University

抄録

A series of thiazole-fused benzothiadiazoles were designed and synthesized, and their structural, electrochemical, and photophysical properties were analyzed. The observed high solubility, in combination with desirably high levels of electron-accepting ability and planarity in the solid state, promises great potential for the application of these compounds as π-electron-accepting building blocks in organic electronic materials. In addition, the two-dimensional expansion of π conjugation through the fused thiazole moiety renders these compounds ideal candidates for use as T-shaped π-conjugation junctions.

収録刊行物

• Chemistry Letters

  Chemistry Letters 43 (8), 1386-1388, 2014-08

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169058984448
• NII論文ID: 130004677577
• DOI: 10.1246/cl.140487
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/43/8/1386/55641103/cl.140487.pdf
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