Synthesis of Glycidamide from Acrylonitrile Using Basic Hydrotalcite Catalyst in the Presence of Aqueous Hydrogen Peroxide and Unsaturated Amide

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  • Shinpei Fujiwara
    School of Materials Science, Japan Advanced Institute of Science and Technology
  • Shun Nishimura
    School of Materials Science, Japan Advanced Institute of Science and Technology
  • Kohki Ebitani
    School of Materials Science, Japan Advanced Institute of Science and Technology

抄録

<jats:title>Abstract</jats:title> <jats:p>Glycidamide (GA) can be synthesized from acrylonitrile (AN) by using hydrotalcite as a solid base catalyst and 25% aqueous H2O2 as an oxidant, in the presence of acrylamide (AA) as a cocatalyst in methanol solvent at 313 K for 18 h. The GA yield and H2O2 utilization efficiency reached 74% and 60%, respectively. The hydrotalcite catalyst could be easily separated from the reaction mixture and reused at least once.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 43 (11), 1716-1718, 2014-08-01

    Oxford University Press (OUP)

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