Synthesis of Glycidamide from Acrylonitrile Using Basic Hydrotalcite Catalyst in the Presence of Aqueous Hydrogen Peroxide and Unsaturated Amide
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- Shinpei Fujiwara
- School of Materials Science, Japan Advanced Institute of Science and Technology
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- Shun Nishimura
- School of Materials Science, Japan Advanced Institute of Science and Technology
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- Kohki Ebitani
- School of Materials Science, Japan Advanced Institute of Science and Technology
抄録
<jats:title>Abstract</jats:title> <jats:p>Glycidamide (GA) can be synthesized from acrylonitrile (AN) by using hydrotalcite as a solid base catalyst and 25% aqueous H2O2 as an oxidant, in the presence of acrylamide (AA) as a cocatalyst in methanol solvent at 313 K for 18 h. The GA yield and H2O2 utilization efficiency reached 74% and 60%, respectively. The hydrotalcite catalyst could be easily separated from the reaction mixture and reused at least once.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 43 (11), 1716-1718, 2014-08-01
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360565169059004288
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- NII論文ID
- 130004677595
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- ISSN
- 13480715
- 03667022
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