Synthesis of Thienothiadiazole–Benzothiadiazole Alternating Copolymers and Their Application to Bulk Heterojunction Solar Cells

DOI PDF 参考文献26件
  • Tomokazu Umeyama
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Yusuke Watanabe
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Tetsushi Miyata
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Hiroshi Imahori
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University

抄録

<jats:title>Abstract</jats:title> <jats:p>Novel conjugated polymers incorporating thieno[3,4-c][1,2,5]thiadiazole (TTD) and 2,1,3-benzothiadiazole (BT) were synthesized. The TTD–BT copolymers displayed broad absorption bands in visible–near-infrared regions with optical band gaps of 1.1–1.2 eV. The HOMO energy levels were lower than those of TTD–oligothiophene alternating copolymers due to the electron-deficient nature of the BT unit. The photovoltaic device consisting of the polymer and a fullerene derivative ([70]PCBM) showed power conversion efficiencies of 0.01–0.08% under simulated AM 1.5G irradiation of 100 mW cm−2.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 43 (12), 1876-1878, 2014-09-30

    Oxford University Press (OUP)

参考文献 (26)*注記

もっと見る

関連プロジェクト

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ