Mimicking the Active Sites of Non-heme Iron Oxygenases on the Solid Supports of Catalysts: Formation of Immobilized Iron Complexes with Imidazolyl and Carboxylate Ligands

• Tomohiro Tsuruta

  Department of Material and Life Chemistry, Kanagawa University

• Tsubasa Yamazaki

  Department of Material and Life Chemistry, Kanagawa University

• Kazuki Watanabe

  Department of Material and Life Chemistry, Kanagawa University

• Yosuke Chiba

  Department of Material and Life Chemistry, Kanagawa University

• Akihiro Yoshida

  Department of Material and Life Chemistry, Kanagawa University

• Shuichi Naito

  Department of Material and Life Chemistry, Kanagawa University

• Jun Nakazawa

  Department of Material and Life Chemistry, Kanagawa University

• Shiro Hikichi

  Department of Material and Life Chemistry, Kanagawa University

抄録

Iron oxygenases mimicking active sites have been constructed on the solid support by anchoring a bis(imidazolyl)borate ligand to carboxylate-functionalized SBA-15 type mesoporous silica gels. Initial loading amounts of an organocarboxylic acid modifier on the silicates affect the hydrocarbon oxygenation catalyses with H2O2 due to changing of the structures of the surface metallocomplex active sites.

収録刊行物

• Chemistry Letters

  Chemistry Letters 44 (2), 144-146, 2014-11-08

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694082323712
• NII論文ID: 130004703978
• DOI: 10.1246/cl.140937
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/2/144/55642526/cl.140937.pdf
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