Solvent Effect on the Fluorescence Response of Hydroxycoumarin Bearing a Dipicolylamine Binding Site to Metal Ions
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- KOBAYASHI Hiroyuki
- Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University
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- KATANO Kohei
- Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University
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- HASHIMOTO Takeshi
- Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University
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- HAYASHITA Takashi
- Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University
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Abstract
The fluorescence behavior of a probe dpa-HC, which has a coumarin derivative that acts as a fluorophore and a dipicolylamine (DPA) unit that functions as a metal ion-recognition site, was investigated with various metal ions in aqueous and several non-aqueous solvents. In aqueous solution, the fluorescence of dpa-HC was enhanced by Zn2+ and Cd2+, but was quenched by other metal ions. On the other hand, in an acetonitrile solution, only Mg2+ enhanced the fluorescence, and the addition of a small amount of water quenched this fluorescence. This dramatic selectivity change is explained by stabilization of a metal-dpa-HC complex due to acetonitrile coordination and ON-OFF switching of the intramolecular photoinduced electron transfer (PET) from the nitrogen lone pair of DPA to the coumarin derivative.
Journal
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- Analytical Sciences
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Analytical Sciences 30 (11), 1045-1050, 2014
The Japan Society for Analytical Chemistry
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Details 詳細情報について
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- CRID
- 1390001204260229632
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- NII Article ID
- 130004704336
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- NII Book ID
- AA10500785
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- ISSN
- 13482246
- 09106340
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- NDL BIB ID
- 025902553
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- PubMed
- 25382039
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed