元素比による石炭の熱分解収率および熱分解生成物の予測

  • 奥村 幸彦
    国立舞鶴工業高等専門学校電子制御工学科
  • 岡崎 健
    東京工業大学大学院理工学研究科機械制御システム専攻

書誌事項

タイトル別名
  • Prediction of Pyrolysis Products and Yields from Brown to Semi-Anthracite Coals by Using Elemental Composition
  • ゲンソヒ ニ ヨル セキタン ノ ネツ ブンカイシュウリツ オヨビ ネツ ブンカイ セイセイブツ ノ ヨソク

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抄録

A coal pyrolysis experiment under atmospheric and elevated pressure conditions using a thermobalance is carried out to clarify the yields of devolatilization products in many coals (i.e., coal ranks from low [C :73.1wt%, daf] to high [C: 90.6 wt%, daf, semi-anthracite]) and to clarify the effect of pressure on pyrolysis yields (tar and gas yields). As a result, a method for predicting the product yields of many coals is presented. Even coal containing almost the same percentage of carbon varies greatly in yield of volatile components and/or tar, but the use of H/C and O/C allows for systematic sorting. The yields of volatile and tar increase almost linearly with increasing H/C. CH4 and C2H4 yields also increase with increasing H/C. The yield of heavier gases such as C2H6, C3H6, and C3H8 cannot, however, be sorted by H/C. CO2 and CO yields are predictable since they increase linearly with increasing O/C. The yields of devolatilization products can be estimated with favorable accuracy for many types of coal by H/C and O/C. In addition, the tar yield decreases and the total yield of gas shows increasing behavior at elevated pressure conditions in all types of coal.

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