Room Temperature Liquid Formulation by Attaching Alkyl Chains on ^|^pi;-Conjugated Molecules
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- Nakanishi Takashi
- International Center for Materials Nanoarchitechtonics (MANA), National Institute for Materials Science (NIMS) Warsaw University of Technology Institute for Molecular Science (IMS)
書誌事項
- タイトル別名
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- Room Temperature Liquid Formulation by Attaching Alkyl Chains on π-Conjugated Molecules
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抄録
Room temperature liquid formulation of intrinsically stiff, optically or optoelectronically active, π-conjugated molecules, such as anthracenes, oligo(p-phenylenevinylenes), and fullerenes, by attaching soft branched long-alkyl chains is demonstrated. Multiple modification with the branched long-alkyl chains on the periphery of an emissive π-conjugated moiety results in isolation of the π-unit core, thus generating a room temperature liquid state with almost no π-π interaction among the adjacent π-units and which shows considerably good luminescence. When only partially wrapping a π-unit core, e.g. C60, attached by branched alkyl chains, those alkyl-π compounds are liquid/amorphous at room temperature, which however, can be directed into assembly by adding either of their own molecular segments, the π-unit or the alkyl-unit (alkane solvents). These ordered materials change from non-photoconductive monomer species to photoconductive assemblies.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 72 (11), 1265-1270, 2014
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680316877696
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- NII論文ID
- 130004749124
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 025901803
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可