電子密度をマッチングさせた浸漬液中での小角X線散乱測定による高速紡糸ポリエチレンテレフタレート繊維の高次構造解析

DOI Web Site 参考文献34件
  • 辻 佳宏
    京都工芸繊維大学大学院工芸科学研究科バイオベースマテリアル学専攻
  • 小島 潤一
    財団法人 化学技術戦略推進機構 研究開発事業部
  • 鞠谷 雄士
    東京工業大学大学院理工学研究科有機・高分子物質専攻
  • 櫻井 伸一
    京都工芸繊維大学大学院工芸科学研究科バイオベースマテリアル学専攻

書誌事項

タイトル別名
  • Analyses of Higher-Order Structures in Poly(Ethylene Terephthalate) Fibers Prepared with High-Speed Melt Spinning by Conducting Small-Angle X-ray Scattering Measurements for Fibers Immersed in Non-Solvent of Which Electron Density was Matched to That of Fibers
  • デンシ ミツド オ マッチング サセタ シンシエキ チュウ デ ノ ショウカク Xセン サンラン ソクテイ ニ ヨル コウソク ボウシ ポリエチレンテレフタレート センイ ノ コウジ コウゾウ カイセキ

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抄録

X-ray total reflection by the surface of fibers produces strong streaks in the direction perpendicular to the fiber axis. In order to analyze higher-order crystalline structures in the fiber, the streaks overwhelm valuable scattering from the structures we intend to analyze. Shish-kebab structure is one of the most important higher-order crystalline structures because it plays a key role for imparting high strength to general fibers. It is known that the streaks due to the X-ray total reflection from the fiber surface can be eliminated by immersing fibers into a liquid of which electron density was matched to that of the PET fibers because the contrast between two neighboring objects is proportional to the square of the electron density difference between the two objects. For the sake of the precise structural analyses, we have conducted two-dimensional small-angle X-ray scattering (2d-SAXS) measurements at room temperature for poly(ethylene terephthalate) (PET) fibers prepared with high-speed melt spinning being immersed in non-solvent of which electron density was matched to that of the PET fibers. For this purpose, a bundle of the fibers was set in a quartz capillary of which axis is parallel to the fibers (the edge-view image). As a consequent, it was found that the spacing between the neighboring shish structures and that between the neighboring kebab structures were both increased with an increase in the spinning velocity. We also present a succeeded example of a sophisticated method for end-view 2d-SAXS measurements for the PET fibers dipped in the electron-density matching non-solvent, where the incident X-ray beam was exposed to the fibers from the direction parallel to the fiber axis. The result of this measurement was consistent with that of the measurements for the fibers in the quartz capillary.

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  • 材料

    材料 64 (1), 11-17, 2015

    公益社団法人 日本材料学会

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