Improved Thin-layer Electrolysis Cell for Ion Transfer at the Liquid|Liquid Interface Using a Conducting Polymer-coated Electrode

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  • YOSHIDA Yumi
    Department of Chemistry and Materials Technology, Kyoto Institute of Technology
  • UCHIDA Junya
    Department of Chemistry and Materials Technology, Kyoto Institute of Technology
  • NAKAMURA Shotaro
    Department of Chemistry and Materials Technology, Kyoto Institute of Technology
  • YAMAGUCHI Satoshi
    Department of Chemistry and Materials Technology, Kyoto Institute of Technology
  • MAEDA Kohji
    Department of Chemistry and Materials Technology, Kyoto Institute of Technology

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This article reviews the development of a thin-layer electrolysis cell with both a thin aqueous phase and a thin organic phase for ion transfer at the liquid|liquid interface for the absolute determination of a redox-inactive ion. In particular, an improvement of the cell performance by using a conducting polymer-coated electrode in the organic phase is discussed. The applicability of the thin-layer electrolysis cell to the absolute determination of redox-inactive ions using the flow-injection method or stripping method is also described.

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  • Analytical Sciences

    Analytical Sciences 30 (3), 351-357, 2014

    社団法人 日本分析化学会

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