Thermochromism of Polydiacetylene with a Hysteresis Loop in the Solid State and in Solution

  • Dei Satoshi
    Department of Applied Chemistry, Graduate School of Engineering, Osaka City University
  • Matsumoto Akikazu
    Department of Applied Chemistry, Graduate School of Engineering, Osaka City University

Abstract

Partly crystalline polydiacetylene 1, which is soluble in many organic solvents at room temperature, was prepared by the solid-state polymerization of 4-methoxybenzyl 10,12-pentacosadiynoate. We found a reversible change in the UV–vis absorption spectrum of 1 in a solid film, polymer matrix, and solution with a hysteresis loop as a function of temperature.

Journal

  • Chemistry Letters

    Chemistry Letters 36 (6), 784-785, 2007

    The Chemical Society of Japan

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