Skeletal Reorganization of Enynes Catalyzed by a Ru(II)–Ru(III) Mixed-valence Complex under an Atmosphere of O<sub>2</sub> or CO

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Author(s)

    • Nakae Takahiro
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • Kamiya Motonobu
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • Fukumoto Yoshiya
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • Chatani Naoto
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

Abstract

A mixed-valence Ru(II)–Ru(III) complex was used to catalyze the skeletal reorganization of 1,6-enynes, leading to the production of 1-vinylcyclopentene derivatives. The reaction proceeded optimally in an atmosphere of O<sub>2</sub> or CO. The presence of an alkyl group at the internal olefinic carbon in the starting enyne resulted in an increase in product yield compared to that bearing no substituent on the olefin moiety.

Journal

  • Chemistry Letters

    Chemistry Letters 42(12), 1565-1567, 2013

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130004867846
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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