Syntheses of Aldol Products and Cyanohydrins from Carboxylic Acids Using Hydrosilanes, Organosilicon Reagents, and Indium Triiodide Catalyst

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  • Yoshihiro Inamoto
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Yoshihiro Nishimoto
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Makoto Yasuda
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Akio Baba
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>Carboxylic acids were applied to an indium triiodide-catalyzed reductive aldol reaction and a reductive cyanation in order to produce aldol adducts and cyanohydrins, respectively, in which the separate addition of two kinds of hydrosilanes was crucial in combination with either ketene silyl acetals or silyl cyanides.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 42 (12), 1551-1553, 2013-09-28

    Oxford University Press (OUP)

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